- A -
Abraded- Worn away
by friction.
Abrasion-
Wear due to friction.
Abrasion Test- Determination
of the rate of wearing away by friction.
Abrasion Tester- A
machine for determining relative abrasion resistance.
Accelerated aging- Intensive
exposure to operating conditions to obtain an early change in
physical properties of an elastomer.
Accelerated life test-
A method designed to approximate in a short time the deteriorating
effects obtained under normal service conditions.
Additive - A material
which does not effect the chemical reaction but is included to
alter the final product such as fillers, flame retardant, etc.
Adhesion-
Basically, the adhering, clinging, bonding or sticking of two
material surfaces to one another, such as polyurethane to polyurethane,
polyurethane to metal, polyurethane to rubber.
Adhesion failure -
The separation of two adjoining surfaces due to service conditions.
Adhesive - A material
which, when applied, will cause two surfaces in contact with each
other to stick together.
Adhesive coating -
A coating applied to a surface to increase its bond to an adjoining
surface.
Aftercure - A continuation
of the stabilization process after the cure has been carried to
the desired degree for a predetermined length of time.
Aging - To undergo
changes in physical properties with age or lapse of time.
Air bomb aging - A
means of accelerating changes in the physical properties of material
by exposing them to the action of air at elevated temperature
and pressure.
Air checks - The
surface markings or depressions which occur due to air trapped
between the material and the mold or pouring surface. (see bubble)
Air oven aging- A
means of accelerating a change in the physical properties of polyurethane
compounds by exposing them to the action of air at an elevated
temperature at atmospheric pressure.
Air trap - See
air checks.
Alloy - A
composite material produced by blending polymers or copolymers
with other polymers under controlled conditions to achieve enhanced
physical properties.
Ambient temperature - The
environment temperature surrounding the object under consideration.
ANSI - American
National Standards Institute
Anti-static - See
static conductive.
Antioxidant - A
compounding ingredient used to retard deterioration caused by
oxygen.
Antiozonant - A
compounding ingredient used to retard deterioration caused by
ozone.
Antislip surface - A
specially treated surface to obtain greater than normal traction.
Aperture -
The clear opening size, as in length, width or diameter of the
opening. Apertures may also involve special shapes such as rectangular
(oblong) or triangular configurations.
Artificial weathering - Exposure
to cyclic laboratory conditions involving changes in temperature,
relative humidity, and radiant energy, with or without direct
water spray, attempting to produce changes in the material similar
to that observed after long-term continuous outdoor exposure.
ASME - American
Society of Mechanical Engineers.
ASTM - American
Society for Testing and Materials.
Average modulus - The
total change of stress divided by the total change of strain.
- B -
Banbury mixer - A
specific type of internal mixer used to incorporate filler and
other ingredients in polyurethane or plastic operations.
Bench test - A
modified service test in which the service conditions are approximated
in the laboratory.
Bending force - The
force required to bend a given cross-section under prescribed
conditions.
Bending modulus - That
force required to induce bending around a specified radius and,
hence, a measure of stiffness.
Bleeding - Migration
to the surface of plasticizer, waxes or similar materials to form
a film or beads. See also Bloom.
Blemish - A mark,
deformity, or injury which impairs the appearance.
Blisters - A raised
spot on the surface or a separation between layers usually forming
a void or air-filled space in the molded article.
Bloom - A discoloration
or change in appearance of the surface of a polyurethane product
caused by the migration of a liquid or solid to the surface. Examples:
sulfur bloom, wax bloom. Not to be confused with dust on the surface
from external sources.
Blow-up- A blister
between plies of a dual durometer article.
Bond - See Adhesion.
Boss - A protuberance
designed to add strength, facilitate alignment, provide fastenings,
etc.
Brand - A mark
or symbol identifying or describing a product and/or manufacturer:
may be either embossed or inlaid.
Breaking strength - The
tensile which polyurethane is at rupture.
Buffing marks - The
characteristic surface condition after a secondary buffing operation.
Butt seam - A seam
made by placing the two pieces to be joined edge to edge.
- C -
Castfilm - A film
made by depositing a layer of polyurethane in solution, or in
a dispersion onto a surface, solidifying and removing the film
from the surface.
Casting - The process
of filling (pouring) open molds with liquid (uncured) polyurethane.
Catalyst -
The ingredient in polyurethane which initiates a chemical reaction
or increases the rate of chemical reaction.
Cement - A mixture
of polymeric compound or elastomer used as an adhesive or sealant.
Cemented edge - An
application of cement around the edge of a fabricated product
with or without internal reinforcement for protection or adhesion.
Chain reaction - Lengthening
of the main chain (backbone) of polymer molecules by end-to-end
attachment.
Chalking - Formation
of a powdery surface condition due to disintegration of surface
binder or elastomer due in turn to weathering or other destructive
environments.
Chalking may be detected by rubbing the film with the fingertip.
It can be measured by rubbing a piece of felt or velvet of contrasting
color across the sample and comparing the amount of chalk picked
up by the cloth with the photographic standards shown in ASTM
D-699.
Checking - Short
shallow cracks on the surface generally due to effect of destructive
action of severe environmental conditions.
Chute lining - Highly
abrasion resistant elastomeric (polyurethane) lining in a chute
to protect the metal chute from abrasion wear.
Coefficient of friction
- The ratio of the force required to move
an object across a surface to the weight of the object.
Cog - A tooth on
the rim of a wheel or polyurethane product.
Cohesive - Tendency
of a material to stick to itself.
Cold flex - See
low temperature flexing.
Cold flexibility - The
relative ease of bending following exposure to low temperature.
Cold flow - Continued
deformation under stress. See Creep.
Cold splice/bond - Usually
the joining of two or more sub-straits together, using a two-part
cement that is chemically cured without using supplemental heat
from an external source. "Cold bond cement" usually
is an uncured mixture of varied elastomers, chemicals, and solvents
that will not self-cure until mixed with an activator to create
a chemical vulcanization (usually exo-thermic).
Commercially smooth - A
degree of smoothness of an article which is acceptable in accordance
with industry practice.
Component - A separately
metered stream of liquid which is introduced directly into the
mixing head.
Compound - A mixture
of a polymer(s) and other materials to give the desired chemical
and physical properties in the elastomeric components of a polyurethane
product.
Compression set - The
deformation in a material remaining after it has been subjected
to and released from a compressive force.
Conductivity -
Quality of power of conducting or transmitting
heat or electricity.
Contact stain - When
staining occurs on the area of an object directly in contact with
the rubber article it is known as "contact stain".
Control - A material
or a product of known characteristics included in a series of
tests to provide a basis for evaluation of other products.
Copolymer - A substance
consisting of molecules characterized by the repetition of two
or more types of monomeric units.
Cracking - A sharp
break or fissure in the surface. Generally due to excessive strain.
Crater - A small
shallow surface imperfection.
Crazing - Crazing
is the phenomenon manifested by slight breaks in the surface.
The break should be called a "crack" if the underlying
surface is visible. For precision evaluation, crazing is described
as "microscopic crazing" (as observed with a stated
magnification, minimum), "visible crazing" (as seen
at close range with the naked eye, 12 inches), and as "distant
crazing" (as seen at 3 feet with the naked eye).
Creep - (1) The
deformation occurring with the lapse of time in both cured and
uncured polyurethane, in a body under stress in addition to the
immediate elastic deformation. Some related terms and properties
are stress-relaxation, hysteresis, damping, flow, compression
set and viscosity. See Cold Flow.
Cross linking - The
formation of chemical links between molecular chains.
Crystallization - A
change in physical properties resulting from the crystalline reorientation
caused by temperature.
Cure - The process
which completes the chemical reaction. The term also refers to
the state of completeness of the chemical reaction.
Cure time - Time
required, at a given temperature, to produce optimum physical
properties in an elastomer.
Curing agent - An
additive that increases chemical activity between the components,
resulting in a increase or decrease in the rate of cure.
Curing temperature - The
temperature at which the elastomer product is cured.
Cut resistance - The
ability of polyurethane to withstand the cutting action of sharp
objects
Cycle time - The
amount of time required to complete a molding cycle including
mold preparation, insert loading (when applicable), release agent
application (when required), mixing and dispensing of components,
reaction (preliminary cure) and demolding.
- D -
Dam - A device
installed within a mold to prevent the flow of material into areas
of the mold cavity to reduce, alter, or eliminate a portion of
the cast part, of which the mold is intended to produce.
Deformation - Any
change of form or shape produced in a body by a stress.
Degradation - A
deleterious change in the chemical structure of a material.
Demold time - The
time period between dispensing the liquid components into the
mold and removing the molded article.
Delamination - The
separation of layers of material in a laminate.
Density - The ratio
of the mass of a body to its volume or the mass per unit volume
of the substance. For ordinary practical purposes, density and
specific gravity may be regarded as equivalent.
Dew point - The
temperature at which a vapor begins to condense.
Diameter - The
length of a straight line passing through the geometric center
to the periphery of an object.
Dip coat - A thin
coat on a surface obtained by dipping the material to be coated
into the coating materials.
Draft - Tapered
relief provided on the vertical element of polyurethane components
to facilitate removal from the mold. The minimum draft angle utilized
in most applications is two degrees per side.
Dumbbell - A test
specimen with lesser width at the middle of its length than at
its ends.
Durometer - An
instrument for measuring the hardness of polyurethane. Measures
the resistance to the penetration of an indentor point into the
surface of rubber.
Durometer hardness - An
arbitrary numerical value which measures the resistance to penetration
of the indentor point of the durometer. Value may be taken immediately
or after a very short specified time.
Dynamic fatigue - Loss
in properties of a material when continually subjected to flexing
and or cyclic stress.
- E -
Elastic limit - The
limiting extent to which a material may be deformed and yet return
to approximately its original shape after removal of the deforming
force.
Elasticity - The
property of an article which tends to return it to its original
shape after deformation.
Elastomer - An
elastic rubber-like substance, such as polyurethane or synthetic
rubber.
Elastomeric properties
- The chemical and physical properties of
an elastomer.
Elongation - Increase
in length before rupture occurs, expressed numerically as a fraction
or percentage of initial length.
Embossing - Operation
of transferring a design to a polyurethane surface.
Exotherm - Heat
generated by a chemical reaction.
Extraction test - A
test in which certain components are separated from a solid by
dissolving them in a liquid solvent under suitable conditions.
Extruded - Forced
through die of tubing machine in either solid or hollow cross
section.
Extrusion - A process
whereby heated or unheated plastic forced through a shaping orifice
becomes a continuously formed piece.
- F -
Family mold - A
multi-cavity mold where each of the cavities forms one of the
component parts of the assembled product.
Fatigue - The weakening
or deterioration of a material caused by a repetition of stress
or strain.
Filler - A material
mixed with a polymer to improve quality or lower cost of a compound.
Film - A sheet
of polyurethane not greater then 0.010" in thickness.
Finger splice - Molded
product with ends cut into mating fingers.
Finish, plate - See
plate finish.
Finish, platen - See
platen finish.
Fire resistance - See
flame retardance.
Fire resistant - Retards
the burning action of fire or flame.
Fisheye - A small
globule that has not blended completely into the surrounding material.
Flame performance - The
manner in which cured polyurethane after being ignited will burn
and/or self extinguish.
Flame retardance - Intensity
of flame diminished by fire retardant ingredient(s) in the polymer
compound.
Flame retardant - A
substance (additive) which is added to a polymer formulation to
reduce or retard its tendency to burn.
Flame test - A
means, under specific condition, for establishing the flame performance
of a polyurethane product. This will not indicate the performance
of the product in any fire in which the product may be involved.
Flange - A raised
edge on a polyurethane article.
Flash - Material
protruding from the surface of a molded part, appearing at the
mold parting line or mold vent points.
Flex cracking - A
surface cracking induced by repeated bending or flexing.
Flex life - The
relative ability of a polyurethane article to withstand dynamic
bending stresses.
Flex life test - A
laboratory method used to determine the life of a plastic product
when subjected to dynamic bending stresses.
Flexibility - The
ability to be bent repeatedly without cracking.
Friction - (1)
The resistance to motion of an object due to the contact between
two surfaces. (2) Improperly used to indicate the bond between
two surfaces.
Friction, coefficient of - The
ratio between the force pressing the surfaces together and the
force required to move it.
Friction, kinetic - The
force which is required to keep a body sliding at a uniform rate.
Also called "friction of motion".
Friction pull - See
adhesion.
Friction, static -
The force which is required to start a body sliding.
- G -
Gel - The initial
semi-solid stage that develops during the solvation of a resin
by a plasticizer.
Gel point - The
stage at which a liquid begins to exhibit pseudo-elastic properties.
Ground finish - Surface
produced by grinding or buffing. See Buffing.
- H -
Hardening - An
increase in resistance to indentation.
Hardness - Property
or extent of being hard. Measured by extent of failure of the
indentor point of any one of a number of standard hardness testing
instruments to penetrate the product.
Haze - The cloudy
appearance of an otherwise transparent film.
Hazing - A dull
finish.
Heat degradation - Change
in chemical and/or physical properties due to excessive exposure
to heat.
Homogenous - Of
uniform composition throughout.
- I -
Immediate set - The
amount of deformation measured immediately after removal of the
load causing the deformation.
Impact - The
single instantaneous stroke or contact of a moving body with another
either moving or at rest, such as a large mass of heavy material
dropping on polyurethane product.
Impact energy - The
effective combination of force (weight of the body and height)
when one body falls on another.
Impact force - The
energy power of impact.
Impact resistance -
The relative ability to withstand mechanical
or physical blows without the loss of protective properties.
Impulse - An application
of force in a manner to produce sudden strain or motion.
Indentation - (1)
The extent of deformation by the indentor point of any one of
a number of standard hardness testing instruments; (2) A recess
in the surface of a polyurethane component.
Injection molding - A
method frequently utilized in the manufacture of polyurethane
products. While this method is extremely cost effective when producing
huge quantities, the properties of the injection molded polymers
(thermoplastics) do not offer the superior characteristics of
"open cast" (thermoset) polyurethane.
ISO - The abbreviation
for the International Organization for Standardization.
- J -
Jaws - Clamps to
hold a specimen when applying stress to the specimen for certain
tests.
Joint - The area
where two ends of a component are fastened together, either by
chemical or mechanical means. See also splice.
- K -
(empty)
- L -
Laminate - A product
made by bonding together two or more layers of material.
Laminated - Build
up from thinner layers.
Lap - A part that
extends over itself or a like part.
Lap seam - A seam
made by placing the edge of one piece of material extending flat
over the edge of the second piece of material.
Lateral - Coming
from the side.
Life test - A laboratory
procedure used to determine the resistance of polymer article
to a specific set of destructive forces or conditions.
Longitudinal - A
lengthwise direction.
Longitudinal seam - A
seam joining two materials in the length of the finished product.
Low spot - A depression
below the general surface of an object.
Low temperature flexibility - The
ability of a polyurethane to be bent or flexed at low temperatures
without loss of serviceability.
Low temperature flexing - The
act of bending a product under conditions of a cold environment.
- M -
Masterbatch - A
preliminary mixture of two or more compound ingredients for purposes
of more thorough dispersion or better processing, and which will
later become part of the final compound in a subsequent mixing
operation.
MDI - The abbreviated
term for diphenylmethane diisocyanate.
Mil - One thousandth
of one inch, 0.001".
Mildew - Mildew
is evidenced by the presence of mold or fungus growth. Two types
are common: (1) Spore type which resembles caviar in appearance.
(2) Mycelium or filament type. A microscope
is necessary to distinguish the spore type from dirt collection.
When it has reached an advanced stage, the mycelium type is often
recognizable with the naked eye, but a microscope is recommended
for any examination of the mildew. Test results show the effect
of mildew is primarily one of appearance and not one of physical
properties.
Mirror finish - A
bright, polished surface appearance.
Mix - See compound
Modulus - (1) A
coefficient or numerical measure of some property. (2) In polymers,
modulus usually refers to one of several measurements of stiffness
or resistance to deformation. The use of the word without modifying
terms may be confusing and such use should not be encouraged.
Modulus in polyurethane may be either static or dynamic; static
moduli are subdivided into tangent, chord, and compounder's. Compounder's
modulus is always in tension, but all the others may be in shear,
compression or tension. Other terms used in connection with "modulus"
are elasticity, rigidity, Young's tangent, and elongation. (3)
All elastic moduli in rubber (except compounder's) are ratios
of stress to the strain produced by that stress, the stress, usually
p.s.i.
Modulus of elasticity - The
force divided by the percent elongation (divided by 100) to cause
the elongation.
Mold lubricant - The
material used to coat the surfaces of a mold to prevent the polyurethane
adhering to the metal during the initial chemical reaction (cure).
Mold mark - An
indentation or embossment on the surface of a molded product caused
by irregularities in the mold surface.
Mold register - The
means used to align the parts of a mold.
Mold release - See
mold lubricant.
MSHA - Abbreviation
for Mine Safety and Health Administration.
- N -
NCO - Abbreviation
for Nitrogen, Carbon, Oxygen.
NDI - Abbreviation
for Napthalene Dilsocyanate.
Nominal - An approximate
amount.
- O -
Oil proof - Not
adversely affected by exposure to oil.
Oil resistant - Withstands
the deterioration effect of oil(generally refers to petroleum)
on the physical properties.
Open cast - The
method of manufacture utilized to obtain maximum wear characteristics
in polyurethane modules.
Optimum cure - The
time and temperature of fusion at which a desired combination
of properties is attained in an elastomer.
Oven - A low pressure
hot air chamber equipped with precise temperature controls, used
for the purpose of POST curing open cast polyurethane products.
See Aging.
Ozone resistant -
Withstands the deteriorating effects of ozone (generally cracking).
- P -
Permanent set -
The amount by which an elastic material fails to return to its
original form after deformation.
Permeability -
The quality or condition of allowing passage of liquids or gases
through a material layer.
Physical properties
- A measure of mechanical characteristics of a material.
Pimple -
A small sharp or conical elevation on the surface of a molded
product.
Pit - A
small crater in the surface of a molded product with width about
the same as its depth.
Plastic -
A material that contains as an essential ingredient one or more
organic polymeric substances of large molecular weight, is solid
in its finished state, can be shaped by flow.
Plasticity -
(1) A measure of the resistance to shear of an uncured elastomer;
(2) a measurement of resistance to shear with heat history.
Plasticizer -
A compounding ingredient which can change the physical and chemical
properties and processibility of a polymeric compound.
Plastisol -
A dispersion of a powderous polymer in a plasticizer.
Plate finish -
A finish resulting from contact with commercially smooth but not
polished heated pouring table.
Polyester -
A polymeric compound, with the reactive hydroxyl groups containing
ester linkages.
Polyether -
A polymeric compound, with the reactive hydroxyl groups containing
ether linkages.
Polymer
- A macromolecular material formed by the chemical combination
of monomers having either the same or different chemical composition.
Polyol -
A chemical compound with more than one reactive hydroxyl group
attached to the molecule.
POST cure
- The period of cure after the product has been removed from the
mold. In many cases, accelerated curing at elevated temperatures
is utilized.
Pot life -
The period of time during which a reacting polymeric compound
remains suitable for its intended use after having been mixed
with a reaction-initiating agent.
Prepolymer
- A chemical intermediate, manufactured by reacting all the isocyanate
with a portion (or all) of the polyol.
PTMEG -
Poly Tetra Methylene Glycol
PU - The
abbreviation for Polyurethane
- Q -
Qualification conformance inspection
- The examination of samples from a production run to determine
conformance to a given specification.
Qualification inspection test -
The examination of samples from a typical production run to determine
conformance to a given specification for approval to become a
supplier
- R -
Recovery
- The degree an elastomeric material returns to its original dimensions
after being stressed.
Reinforcement -
The strengthening member of a polyurethane component.
Reinforcement agent -
An ingredient in a polymeric compound used to increase its chemical
and physical properties.
Reinforcing element
- The strengthening members of polyurethane component or product.
Resin -
Certain materials produced by chemical synthesis.
Resistance -
The property or ability of matter to withstand the effects of
force, pressure, heat or chemical action.
- S -
Sample -
A piece of material removed for evaluation.
Scraper
- A open cast polyurethane device for cleaning the surface of
conveyor belting.
Seam - The
place where two edges of fabric or elastomer are adjacent to each
other to form a single ply or layer.
Semi-cure -
A partial or incomplete cure.
Service test -
A test in which the product is made to operate under service conditions
in the actual equipment.
Set - The
amount of deformation remaining after complete release of the
load producing the deformation.
Sheeting -
A form of plastic in which the thickness is very small in proportion
to length and width and in which the plastic is present as a continuous
phase throughout.
Shelf storage life -
The period of time prior to use during which a product retains
its intended performance capability.
Shore hardness -
The scale by which a polyurethane screen module or component is
measured for hardness, typically expressed as "shore A".
As the hardness is increased, abrasion resistance tends to increase
while impact resistance decreases proportionately. As the hardness
is decreased, abrasion resistance tends to decrease while impact
resistance increases proportionately.
Shrinkage
- The difference found on a molded part as compared to the actual
mold cavity dimension. The typical shrinkage for thermoset polyurethane
is about 2%.
Simulated service test -
See bench test.
Sink - A
collapsed blister or bubble leaving a depression in a product.
Skive -
A cut made on an angle to the surface to produce a tapered or
feathered cut.
Specification -
Detail description of specific requirements.
Specimen -
A piece cut from a sample of polyurethane to test.
Static conductive -
Capability to conduct static electricity.
Static electricity -
Electrical potential resulting from two surfaces rubbing together
or parting one from the other.
Static friction -
The resistance which must be overcome to start a body sliding
down a surface.
Stiffness -
Resistance to flexing.
Strain -
Deformation resulting from a force applied to a body.
Stress -
Force applied to a body that results in the body being deformed.
Stretch -
An increase in length.
Sun check -
Fine cracks and crazing of an elastomeric surface primarily due
to the sun's ultraviolet rays.
- T -
Tack - Having
a property of temporary adhesion.
Tear Propagation -
Continuation of tear.
Tensile strength
- The maximum force, stress, applied to a specimen at rupture.
Tensile stress
- The force applied to stretch a test piece (specimen).
Tension -
Stress on a material tending to cause extension of the material.
TDI - Abbreviation
for Toluene Dilsocyanate.
Thermoplastic -
Capable of being repeatedly softened by heating and hardened by
cooling and in the softened state can be shaped by flow.
Thermoset -
A material that can undergo a chemical reaction by the action
of heat or catalyst, leading to a relatively infusible and cross-linked
state. Thermoset polyurethane is not altered by elevated temperatures
until reaching the decomposition point.
Tolerances
- The limiting values for a dimension.
Trapped air -
Air which is enclosed in a product or between a product and a
mold surface during cure.
- U -
Ultimate elongation
- Elongation at rupture.
Ultimate strength -
The force required to rupture a specimen.
Ultimate tensile
- Tensile stress at rupture.
Undercure
- A less than optimal state of cure which may be evidenced by
tackiness or inferior physical properties.
- V -
Viscosity -
The flow property of a material. The lower the number, the thinner
the liquid.
Void - The
absence of material or an area devoid of materials where not intended.
See also blister and sink.
- W -
Warpage
- Dimensional distortion in a molded product.
Weathering -
Surface deterioration, evidenced by cracks and crazing of an elastomer,
during outdoor exposure.
- X -
(empty)
- Y -
Yield point -
The stress in a material at which a substantial increase in strain
occurs with a minimum increase in stress.
Yield strength
- The stress at which a material exhibits a specified limiting
permanent set. Determined by a measurable value of plastic yielding
of the material, above which the material is considered to be
damaged and below which the damaging effects are considered to
be negligible.
- Z -
Zero load
- A reference load applied in taking an initial reading and prior
to determining compressibility or extensibility.
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